Binding interactions between the host cucurbit[7]uril and dendrimer guests containing a single ferrocenyl residue.
نویسندگان
چکیده
The stability of the inclusion complexes formed between the host cucurbit[7]uril and dendrimers containing a single ferrocene residue is strongly affected by the solution pH and the growth of the dendrimer, reaching its highest values on the second and third generation dendrimers, whereas no complex is formed with the first generation compound.
منابع مشابه
Probing the tolerance of cucurbit[7]uril inclusion complexes to small structural changes in the guest.
The binding properties of the cucurbit[7]uril host with three structurally related ferrocene-containing guests, ferrocenyltrimethylammonium, ferrocenylmethyltrimethylammonium and ferrocenylethyltrimethylammonium, have been investigated using (1)H NMR spectroscopy, mass spectrometry, voltammetry and computational methods. The experimental and computational data indicate that the stability of the...
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ورودعنوان ژورنال:
- Chemical communications
دوره 40 شماره
صفحات -
تاریخ انتشار 2005